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Preparation of Supported Nanosized Sulfated Zirconia by Strontia and Assessment of Its Activities in the Esterification of Oleic Acid

机译:锶制备负载型纳米硫酸锆及其对油酸酯化活性的评价

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摘要

The aim of this study was to examine a new nanocatalyst of SrO/S-ZrO2 in esterification reaction and the optimum value of strontia loading over the sulfated zirconia. The sulfated zirconia was supported with different molar ratios of strontia in the range of 0.0–0.30, using the solvent-free method. The samples were characterized using XRD, FT-IR, BET and TEM analysis and their activity were investigated in esterification reaction of oleic acid. The findings of this study revealed that 25 mol % SrO/S-ZrO2 had the highest yield in the esterification reaction. It was also concluded that strontia-supported sulfated zirconia could improve the low reusability of the catalyst. Furthermore, 95 % conversion was also obtained at optimized conditions (i.e., 100 °C, 2 wt. % of catalyst, 6:1 molar ratio of methanol/oleic acid and for a period of 30 minutes).
机译:这项研究的目的是研究酯化反应中一种新型的SrO / S-ZrO2纳米催化剂以及硫酸盐氧化锆上的锶负载量的最佳值。使用无溶剂方法,以0.0-0.30范围内的不同锶摩尔比负载硫酸化氧化锆。用XRD,FT-IR,BET和TEM分析对样品进行表征,并研究其在油酸酯化反应中的活性。该研究的发现表明,在酯化反应中25mol%的SrO / S-ZrO2具有最高的收率。还得出结论,锶负载硫酸盐氧化锆可以改善催化剂的低可重复使用性。此外,在最佳条件下(即100℃,催化剂的2重量%,甲醇/油酸的摩尔比为6∶1,持续30分钟)也获得了95%的转化率。

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